Pursuit of an Electron Deficient Titanium Nitride
Date Issued
2021-04
Author(s) USM
Pinter, Balazs
DOI
10.1021/acs.inorgchem.0c03644
Abstract
The nitride salt [(PN)(2)Ti equivalent to N{mu(2)-K(OEt2)}](2) (1) (PN- = (N-(2-(PPr2)-Pr-i-4-methylphenyl)-2,4,6-Me3C6H2) can be oxidized with two equiv of I-2 or four equiv of ClCPh3 to produce the phosphinimide-halide complexes (NPN)(PN)Ti-(X) (X- = I
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